EGU Blogs

Matt Herod

Matt Herod is a Ph.D Candidate in the Department of Earth Sciences at the University of Ottawa in Ontario, Canada. His research focuses on the geochemistry of iodine and the radioactive isotope iodine-129. His work involves characterizing the cycle and sources of 129I in the Canadian Arctic and applying this to long term radioactive waste disposal and the effect of Fukushima fallout. His project includes field work and lab work at the André E. Lalonde 3MV AMS Laboratory. Matt blogs about any topic in geology that interests him, and attempts to make these topics understandable to everyone. Tweets as @GeoHerod.

My EGU2013 (Tuesday)

Firstly, I am not actually attending EGU 2013 this year. However, that does not mean I can’t participate. In fact, it has been incredibly easy for to me join in, although I have had to wake up very early in the morning to make up for the time difference between Vienna and Ottawa.

I took part in two press conferences on Tuesday. The first called: The consequences of nuclear accidents: Fukushima and Europe and promised to be extremely interesting especially from my point of view as a researcher of environmental radionuclides. In fact, I was tuned in for more than just the EGU blogging part since I am in the midst of a project investigating the effects of Fukushima here in Canada and the transport of radionuclides from the accident. I intend to present the work at Goldschmidt later this year and write a publication on it which will comprise a part of my thesis.

The session was started by Dr. Yuichi Onda from the Centre for Research in Isotopes and Environmental Dynamics at the University of Tsukuba.

Dr. Onda and his group are studying the transfer and fallout of Fukushima radionuclides in every aspect of the environment. This is an incredibly daunting task. The infrastructure required to sample so many different environmental reservoirs is mind-boggling and Dr. Onda showed in several of his slides how tough it could be. The group sampled trees, soil, soil water, soil erosion, water in both cultivated and non cultivated environments, sediment in rivers and lakes as well as transport between these reservoirs and then finally the transport to the ocean from all of these sources. Basically, they set up one bad-a$$ monitoring network!

The conclusions from this network were that the deposition process of the radionuclides began by falling on trees but then over time washes off and between .2 and 3.5% of the fallout washes into streams and rivers where it is then transported to the oceans. In a very basic way it kind of looked like this:

File:HydrologicalCycle1.png

Source: Wikipedia

The next speaker was Dr. Kazuyuki Kita from Ibaraki University. He was explaining one step earlier in the whole transport process than Dr. Onda since Dr. Kita’s focus is on the atmospheric transport and dispersion of radionuclides from Fuksuhima. Basically, once the accident occured tons of radionuclides were released into the atmosphere and blown hither and yon until they are eventually deposited in rain or adsorbed onto aerosols and settle because of gravity’s relentless nature. They can also be re-suspended after the fact. This is particularly common with iodine (I know about this one…) Dr. Kita then went on to show a picture of the fallout of cesium-137 over Japan, which is pictured below. Furthermore, the measured concentrations agreed very well with the predictions made by atmospheric modelling, which is a tricky business at the best of time, but must be even more so when the entire world is breathing down your neck asking where will the radionuclides go? The difference were due to rainout, which is difficult to predict.

Slide from Dr. Kita’s talk showing the actual fallout vs. the modelled fallout.

Dr. Kita then went on to talk about the variation of radionuclides in the atmosphere over time following the accident  and the influence of re-suspension on radionuclides sitting on the land surface. He showed this graph which illustrates very clearly how 137Cs and 134Cs concentrations spiked following the accident and then declined over time. However, if you look in October you can see that the levels start to rise again, which Dr. Kita attributes to re-suspension. Furthermore, these peaks were coincident with the transport of air parcels from Fukushima as well making it certain that this was the source of the radionuclides. Another source of radionuclides since the disaster has been the re-emission of iodine and cesium from the ocean surface as well.

A slide from Dr. Kita’s talk showing the temporal trend in cesium fallout from Fukushima.

The final talk of the press conference was by Dr. Petra Seibert from the University of Vienna. Dr. Seibert, a meteorologist, gave a truly fascinating, yet somewhat scary talk about how prepared (or not) Europe is for nuclear accidents and the consequences they have with context from both Fukushima and Chernobyl. Dr. Seibert makes the point that despite ample opportunity to learn from our nuclear mistakes we have not addressed all of the deficiencies that exist.

Concerning Fukushima, Dr. Seibert points out that the dispersion of radionuclides from the nuclear plant is not simple and results in contamination outside of predicted zones. This means that the evacuation pattern of simply evacuating people in concentric circles depending on the distance from the plant is not a very effective way of ensuring that people are not affected since the atmospheric spread of radionuclides is not circular. Therefore, in order to be prepared for potential disasters a predictive model of dispersion is needed. Dr. Seibert has developed such a model and shows some of the incredibly variable, and somewhat artistic, results in the following image. The blank space shows a movie of a very complex dispersion.

A slide from Dr. Seibert’s talk showing the incredibly variable nature of radionuclide dispersion from a point source.

Dr. Seibert’s ultimate point is that despite what we have learned from Fukushima and Chernobyl we are not yet prepared enough to handle another large nuclear disaster. Indeed, she makes the point that one in Europe could result in continental scale contamination and that in order to prepare for this proactive measures like iodine tablets should be widely distributed. Furthermore, data distribution and communication between organizations and nations is not adequate as well, which would only serve to exacerbate the seriousness of a nuclear accident should one occur.

In my opinion to keys to avoiding another Chernobyl or Fukushima lies in open communication and learning everything we can from these two disasters. However, I put it to you, what do we still need to learn? What are our shortcomings when if comes to disaster preparedness. Do you agree with measures like iodine distribution in order to mitigate the risk from another accident or should we just cease nuclear energy production entirely?

I also tuned into the fantastic press conference on the Chelyabinsk meteorite fall, but Jon has covered it excellently so head over to his blog a for a summary of it. If you would like to watch the livestream of the press conference for yourself it can be found here: http://streams.h82.eu/EGU2013/index.php?modid=18&a=show&pid=206

 

Geology Photo of the Week #29

The photo this week is of another self collected beauty. I collected this piece below at the Marmoraton Iron Mine in Marmora, Ontario a few years ago. When I found it none of the garnet crystals you see were visible. They were all covered by a thick layer of calcite. I could just make out the edge of a broken crystal at the side. However, I have been collecting at Marmora a lot and I knew that this had the possibility to turn out beautifully since at this quarry calcite often hides terrific and undamaged crystals below. You can still make out a little bit of it here and there (it is yellowish white). The key is to just get rid of it. Luckily, for me and many other collectors of Marmora minerals calcite dissolves easily in hydrochloric acid. So cleaning a find like this becomes a simple matter of placing it in a basin of HCl and waiting for the magic (chemistry)  to happen. After a few days, and a few changes of the acid the result is what you see pictured below: a beautiful cluster of 1-1.5cm grossular garnet crystals, with some magnetite veins, minor epidote and left over calcite.

(Photo: Matt Herod)

 Unfortunately, the garnet crystals of Marmora are not gem quality or anywhere near it, but they do form very attractive crystals of which I have a large, large number after years of collecting there. Marmora is also a great place to collect epidote, pyrite, calcite, pyrolusite, magentite, ilmenite, marcasite and actinolite. All of which are common and relatively easy to find with a bit of work. e.g. sledgehammering.

The quarry is larger than the town of Marmora!

Cheers,

Matt

p.s. Watch this space for EGU2013 updates starting tomorrow!! I’m really looking forward to the Fukushima press conference.

Geology Photo of the Week #28

Happy April Fools/Easter everyone! I know that I am a day late, but yesterday was a holiday in Canada. Spring is also in the air, not today actually since it is -7 currently, but we have no more snow, and we had a few nice days over the Easter weekend. It is therefore appropriate for the photo of the week to be something eggy.

A piece of Pleistocene emu egg shell. Found near an ancient aboriginal campground in South Australia. (Photo: Matt Herod)

This photo is of a fragment of Pleistocene age emu egg shell that was found in Port Augusta, South Australia.

Bonus Photo: The duck-billed platypus, a monotreme and one only two types of egg laying mammal in the world.

Platypus (Photo: Matt Herod)

Cheers,

Matt

It’s rainin’ isotopes…

This post is kind of a continuation of Laura Roberts excellent guest post on the Solar Storms and the Earth’s Magnetic field. However, this is a bit of a different spin on it. I am not writing about what get’s kept out, but rather what slips by the shield and gets in. Of course, I am speaking about cosmic rays and the wonderfully useful isotopes they produce that rain down upon us. Yes, it is literally raining isotopes…all the time! I know that this sounds weird, when I first learned about this phenomenon it came as a complete surprise to me. Not only are isotopes raining down all the time, but there is a lot that we can learn about our planet by analyzing these  amazing by-products of cosmic ray collisions.

What are cosmic rays?

Cosmic rays are incredible things. The Earth is constantly being bombarded by them and we are protected from this massive influx of extra-terrestrial radiation by our magnetic field and atmosphere, which deflects about 90% of the low energy cosmic rays. Check out last weeks awesome guest post about Earth’s magnetic field. There are two types of cosmic rays. Primary cosmic rays generally originate outside of our solar system and travel throughout space occasionally bumping into things like planets. In fact, it has only recently been discovered exactly where they come from. In February, 2013 a paper came out in Science called: Evidence Shows That Cosmic Rays Come From Exploding Stars that (surprise) stated primary cosmic rays are produced by exploding stars aka. supernovae in which an ancient star blows up, releasing massive amounts of energy, elements and cosmic rays!

File:Keplers supernova.jpg

Kepler’s Supernova (Source)

Primary cosmic rays are 99% protons and alpha particles (two protons and two neutrons) and the remaining 1% are the nuclei of heavy atoms or beta particles (electrons). These bits of atoms and radiation fly around in space and bang into everything. Sometimes, actually more often than sometimes, they bang into the Earth. In fact, they bang into the Earth a lot! There are billions of collisions every day. Some of the particles crashing into the Earth have low energies while others have high energies. The frequency that these low energy particles collide is many times greater than high energy ones. There are about 10,000 collisions per square meter per second for giga-eletronvolt particles. For the higher energy rays the rate of collision is less. They might arrive with a frequency of 1 per square metre per second, as is the case with tera-electronvolt particles. The decrease in collision frequency continues as energy increases up until the very highest energy of the exa-electronvolt which collides about 0nce per square kilometre per century.

When cosmic rays pass through the Earth’s magnetic field is when things start to get really interesting, from a geochemical perspective that is. When primary cosmic rays enter the Earth’s atmosphere they start banging into all of the molecules and atoms floating around up there and produce secondary cosmic rays. Basically imagine a bowler throwing a strike. The bowling ball represents the primary cosmic ray and the pins are the molecules in the atmosphere. When the ball collides with the pins they fly off in every direction, which is analogous to the process occurring constantly in our atmosphere. When this takes place in the atmosphere the collision is so energetic the molecules and atoms can actually break apart. This is called spallation and results in a cascade of neutrons, protons and atoms called an air shower.

File:Protonshower.jpg

A simulation of a cosmic ray shower formed when a proton with 1TeV (1e^12 eV) of energy hits the atmosphere about 20km above the ground. The ground shown here is a 8km x 8km map of Chicago’s lakefront. This visualization was made by Dinoj Surendran, Mark SubbaRao, and Randy Landsberg of the COSMUS group at the University of Chicago, with the help of physicists at the Kavli Institute for Cosmological Physics and the Pierre Auger Observatory. (Source)

What is produced?

Air showers produce all sort of radioactive isotopes that are formed no other way. Some are very short lived and decay away quickly, while others are extremely long lived and have half lives of millions of years, allowing them to accumulate in the environment.

A list of the major cosmic ray isotopes and their half lives. The ones in bold have geologic applications.

Other isotopes are produced when cosmic rays reach the ground and collide with minerals. This can cause other isotopes to form within the mineral crystal lattice. For example, the cosmogenic isotope, aluminum-26 is produced when a cosmic rays strikes a quartz crystal and transforms some of the silicon in the quartz structure into aluminum. These are referred to as in-situ cosmogenic isotopes.

The next part of the process concerns what happens to all of these isotopes once they have sprung into existence thousands of metres above our heads. The fate of these isotopes is varied and they all live in the atmosphere for a little while before becoming part of the hydrologic cycle. Eventually they fall down to Earth either stuck onto aerosols or incorporated into rain and begin to interact with water bodies, enter groundwater, stick to soil particles or get absorbed into people, plants or animals. Essentially, they begin cycling through the environment until they decay away. Since these isotopes get cycled through various parts of the environment we can use them as tracking tools to trace the pathways they take and learn about their interactions with other components of environmental cycles.

What is the use?

Cosmic rays isotopes are useful for more than just getting a good tan! In fact, the list of possible questions that can be applied to cosmogenic isotopes just goes on and on. I’ll just briefly cover a few of them since each one of these applications is a whole blog post by itself I’ll just give the highlights here.

Exposure age dating: Exposure age dating is one of the principle uses of cosmogenic isotopes and several different ones have been employed to this end. Exposure age dating is when we use cosmogenic isotopes to date how long something has been exposed to secondary cosmic rays at the Earth’s surface. For example, a rock at the toe of a glacier may have just been exposed to cosmic rays a year ago and its exposure age date will tell us this. Another rock, 20 metres further from the glacier toe may have been exposed 5 years ago and this difference will be recorded. Basically, the clock starts ticking once cosmic rays are able to reach the rock or bone, or whatever material is being dated. Exposure age dating has the power to date materials that range from only a few thousand years to millions of years depending on the half lives and concentrations of the nuclides in question. The way exposure dating works is that when a secondary cosmic ray impacts a rock containing Si (silicon) or O (oxygen) some of the neutrons on the silicon or oxygen are knocked off and the result is the production of aluminum-26 or beryllium-10 right in the mineral lattice. One common mineral that contains both silicon and oxygen is quartz. Quartz is pretty much everywhere and in everything, which opens the door for a wide range of materials that can be exposure age dated. All they have to contain is a bit of quartz. The decay of 26Al and 10Be allows the material to be dated. There are other isotopes that can be used for exposure age dating besides these two and other minerals that contain Si or O can also be used as well. The figure below shows the wide range of applications that exposure age dating can be applied to. For example, if you want to date a volcanic eruption it is easy to exposure age date the lava or ash, both of which have a lot of Si. It is also possible to date landslides, erosion rates, burial ages, the list goes on and on. There are many other isotopes that can be used as well besides 26Al and 10Be.

CLOUD Project: The CLOUD project is a CERN experiment that is investigating the possible linkage between cosmic rays and cloud formation. It has been hypothesized that cosmic rays can cause clouds to form by forming aerosols and it has been noticed by satellites that an increase in the cosmic ray bombardment can increase the amount of cloud cover. Cloud cover has a profound influence on the Earth’s energy balance and hence climate. It has been proposed that throughout geologic time changes in the cosmic ray flux have been responsible for climate change. However, proving this is difficult given the length of time in question and the evolving states of the cosmic ray flux and Earth’s magnetic field. However, CLOUD has set out to find the linkage between cosmic rays, clouds and climate if one exists.

Carbon-14: Carbon 14 is unquestionably the most used of any of the cosmogenic isotopes. It has applications in geology, archaeology, paleontology, anthropology, hydrogeology, and many other -ologies as well. 14C is produced primarily when neutrons collide with nitrogen in the atmosphere replacing a proton in the nitrogen nucleus and transforming it into carbon-14, although atmospheric nuclear weapons testing also produced a substantial amount of 14C. The primary use of 14C, or radiocarbon, is radiocarbon dating. Once radiocarbon is produced it enters the global carbon cycle and disperses throughout the environment. Since it is part of the carbon cycle it becomes incorporated into all living things, including people and animals. 14C continues to enter our bodies while we are alive. Once we die, there is no further addition of 14C and therefore, the clock starts ticking on its use as a dating tool. 14C has a 5,730 year half life and is therefore useful as a dating tool for biological materials up to ~45,000 years ago.

Cosmic rays are some of the most mysterious, yet useful phenomena on our planet and have allowed for incredible advances in many sciences. As new, more sensitive technology becomes available look for the use of cosmic rays and the isotopes they produce to accelerate as we find new questions they can be used to answer.

Cheers and thanks for reading,

Matt